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Solvent tuning of photochemistry upon excited-state symmetry breaking

The nature of the electronic excited state of many symmetric multibranched donor–acceptor molecules varies from delocalized/multipolar to localized/dipolar depending on the environment. Solvent-driven localization breaks the symmetry and traps the exciton in one branch. Using a combination of ultraf...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Dereka, Bogdan, Svechkarev, Denis, Rosspeintner, Arnulf, Aster, Alexander, Lunzer, Markus, Liska, Robert, Mohs, Aaron M., Vauthey, Eric
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7174366/
https://ncbi.nlm.nih.gov/pubmed/32317631
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-15681-3
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