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Palladium-catalysed C–F alumination of fluorobenzenes: mechanistic diversity and origin of selectivity

A palladium pre-catalyst, [Pd(PCy(3))(2)] is reported for the efficient and selective C–F alumination of fluorobenzenes with the aluminium(i) reagent [{(ArNCMe)(2)CH}Al] (1, Ar = 2,6-di-iso-propylphenyl). The catalytic protocol results in the transformation of sp(2) C–F bonds to sp(2) C–Al bonds and...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Rekhroukh, Feriel, Chen, Wenyi, Brown, Ryan K., White, Andrew J. P., Crimmin, Mark R.
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163258/
https://ncbi.nlm.nih.gov/pubmed/34094156
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01915a
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