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Palladium-catalysed C–F alumination of fluorobenzenes: mechanistic diversity and origin of selectivity
A palladium pre-catalyst, [Pd(PCy(3))(2)] is reported for the efficient and selective C–F alumination of fluorobenzenes with the aluminium(i) reagent [{(ArNCMe)(2)CH}Al] (1, Ar = 2,6-di-iso-propylphenyl). The catalytic protocol results in the transformation of sp(2) C–F bonds to sp(2) C–Al bonds and...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8163258/ https://ncbi.nlm.nih.gov/pubmed/34094156 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01915a |
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