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Mechanistic insights into boron-catalysed direct amidation reactions

The generally accepted monoacyloxyboron mechanism of boron-catalysed direct amidation is brought into question in this study, and new alternatives are proposed. We have carried out a detailed investigation of boron-catalysed amidation reactions, through study of the interaction between amines/carbox...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Arkhipenko, Sergey, Sabatini, Marco T., Batsanov, Andrei S., Karaluka, Valerija, Sheppard, Tom D., Rzepa, Henry S., Whiting, Andrew
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5890798/
https://ncbi.nlm.nih.gov/pubmed/29675153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03595k
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