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Assessing long-range contributions to the charge asymmetry of ion adsorption at the air–water interface

Anions generally associate more favorably with the air–water interface than cations. In addition to solute size and polarizability, the intrinsic structure of the unperturbed interface has been discussed as an important contributor to this bias. Here we assess quantitatively the role that intrinsic...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Cox, Stephen J., Thorpe, Dayton G., Shaffer, Patrick R., Geissler, Phillip L.
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society of Chemistry 2020
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162909/
https://ncbi.nlm.nih.gov/pubmed/34094413
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01947j
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