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Elucidating the mechanism of selective ion adsorption to the liquid water surface
Adsorption of aqueous thiocyanate ions from bulk solution to the liquid/vapor interface was measured as a function of temperature by resonant UV second harmonic generation spectroscopy. The resulting adsorption enthalpy and entropy changes of this prototypical chaotrope were both determined to be ne...
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| Auteurs principaux: | , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
National Academy of Sciences
2012
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3271925/ https://ncbi.nlm.nih.gov/pubmed/22233805 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1116169109 |
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