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Elucidating the mechanism of selective ion adsorption to the liquid water surface

Adsorption of aqueous thiocyanate ions from bulk solution to the liquid/vapor interface was measured as a function of temperature by resonant UV second harmonic generation spectroscopy. The resulting adsorption enthalpy and entropy changes of this prototypical chaotrope were both determined to be ne...

Πλήρης περιγραφή

Αποθηκεύτηκε σε:
Λεπτομέρειες βιβλιογραφικής εγγραφής
Κύριοι συγγραφείς: Otten, Dale E., Shaffer, Patrick R., Geissler, Phillip L., Saykally, Richard J.
Μορφή: Artigo
Γλώσσα:Inglês
Έκδοση: National Academy of Sciences 2012
Θέματα:
Διαθέσιμο Online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3271925/
https://ncbi.nlm.nih.gov/pubmed/22233805
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1116169109
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