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Elucidating the mechanism of selective ion adsorption to the liquid water surface

Adsorption of aqueous thiocyanate ions from bulk solution to the liquid/vapor interface was measured as a function of temperature by resonant UV second harmonic generation spectroscopy. The resulting adsorption enthalpy and entropy changes of this prototypical chaotrope were both determined to be ne...

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Main Authors: Otten, Dale E., Shaffer, Patrick R., Geissler, Phillip L., Saykally, Richard J.
Formáid: Artigo
Teanga:Inglês
Foilsithe: National Academy of Sciences 2012
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3271925/
https://ncbi.nlm.nih.gov/pubmed/22233805
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1116169109
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