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Chemo-selective cross reaction of two enals via carbene-catalyzed dual activation
A dual catalytic chemo-selective cross-coupling reaction of two enals is developed. One enal (without α-substitution) is activated by an NHC catalyst to form an acylazolium enolate intermediate that undergoes Michael-type addition to another enal molecule bearing an alkynyl substituent. Mechanistic...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
The Royal Society of Chemistry
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162827/ https://ncbi.nlm.nih.gov/pubmed/34123233 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03297b |
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