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Chemo-selective cross reaction of two enals via carbene-catalyzed dual activation
A dual catalytic chemo-selective cross-coupling reaction of two enals is developed. One enal (without α-substitution) is activated by an NHC catalyst to form an acylazolium enolate intermediate that undergoes Michael-type addition to another enal molecule bearing an alkynyl substituent. Mechanistic...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162827/ https://ncbi.nlm.nih.gov/pubmed/34123233 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03297b |
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