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Acyclic diaminocarbene-based Thiele, Chichibabin, and Müller hydrocarbons
Thiele, Chichibabin and Müller hydrocarbons are considered as classical Kekulé diradicaloids. Herein we report the synthesis and characterization of acyclic diaminocarbene (ADC)-based Thiele, Chichibabin, and Müller hydrocarbons. The calculated singlet–triplet energy gaps are ΔE(S–T) = −27.96, −3.70...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162802/ https://ncbi.nlm.nih.gov/pubmed/34123209 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03622f |
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