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Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt(iv) hydrides

Hydride complexes resulting from the oxidative addition of C–H bonds are intermediates in hydrocarbon activation and functionalization reactions. The discovery of metal systems that enable their direct formation through photoexcitation with visible light could lead to advantageous synthetic methodol...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Poveda, Dionisio, Vivancos, Ángela, Bautista, Delia, González-Herrero, Pablo
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162800/
https://ncbi.nlm.nih.gov/pubmed/34123220
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04879h
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