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Carbonate-promoted C–H carboxylation of electron-rich heteroarenes

C–H carboxylation is an attractive transformation for both streamlining synthesis and valorizing CO(2). The high bond strength and very low acidity of most C–H bonds, as well as the low reactivity of CO(2), present fundamental challenges for this chemistry. Conventional methods for carboxylation of...

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Publicat a:Chem Sci
Autors principals: Porter, Tyler M., Kanan, Matthew W.
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162799/
https://ncbi.nlm.nih.gov/pubmed/34123214
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04548a
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