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A modular and divergent approach to spirocyclic pyrrolidines

An efficient three-step sequence to afford a valuable class of spirocyclic pyrrolidines is reported. A reductive cleavage/Horner–Wadsworth–Emmons cascade facilitates the spirocyclisation of a range of isoxazolines bearing a distal β-ketophosphonate. The spirocyclisation precursors are elaborated in...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Shennan, Benjamin D. A., Smith, Peter W., Ogura, Yusuke, Dixon, Darren J.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162384/
https://ncbi.nlm.nih.gov/pubmed/34094297
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03676e
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