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Annulative π-extension of BODIPYs made easy via gold(i)-catalyzed cycloisomerization

Here we report gold(i)-catalyzed cycloisomerization as a new powerful synthetic tool for the preparation of π-extended BODIPY derivatives. The catalytic system PPh(F)(3)AuCl/AgSbF(6) enables the synthesis of [b]-[2,1]naphtho-fused-BODIPYs (2a–2c) under mild conditions, in excellent yields and short...

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Publicado en:Chem Sci
Main Authors: Labella, Jorge, Durán-Sampedro, Gonzalo, Martínez-Díaz, M. Victoria, Torres, Tomás
Formato: Artigo
Idioma:Inglês
Publicado: The Royal Society of Chemistry 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162369/
https://ncbi.nlm.nih.gov/pubmed/34094331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01054e
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