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Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

Palladium-catalyzed regioselective di- or mono-arylation of o-carboranes was achieved using weakly coordinating amides at room temperature. Therefore, a series of B(3,4)-diarylated and B(3)-monoarylated o-carboranes anchored with valuable functional groups were accessed for the first time. This stra...

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Publicat a:Chem Sci
Autors principals: Liang, Yu-Feng, Yang, Long, Jei, Becky Bongsuiru, Kuniyil, Rositha, Ackermann, Lutz
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162305/
https://ncbi.nlm.nih.gov/pubmed/34094330
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01515f
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