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Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity

The Simmons–Smith reaction offers a direct route for conversion of an alkene into a cyclopropane with a zinc carbenoid as the active intermediate. Zinc carbenoids, however, have never delivered a methylene unit to substrates with metal–carbon multiple bonds. Herein, we describe this type of reaction...

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Publicat a:Chem Sci
Autors principals: Huang, Fanping, Zheng, Xuejuan, Lin, Xinlei, Ding, Linting, Zhuo, Qingde, Wen, Ting Bin, Zhang, Hong, Xia, Haiping
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162146/
https://ncbi.nlm.nih.gov/pubmed/34094279
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03215h
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