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Transformations of the cyclo-P(4) ligand in [Cp′′′Co(η(4)-P(4))]

The reactivity of the cyclo-P(4) ligand complex [Cp′′′Co(η(4)-P(4))] (1) (Cp′′′ = 1,2,4-tri-tert-butyl-cyclopentadienyl) towards reduction and main group nucleophiles was investigated. By using K[CpFe(CO)(2)], a selective reduction to the dianionic complex [(Cp′′′Co)(2)(μ,η(3):η(3)-P(8))](2−) (2) wa...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Piesch, Martin, Seidl, Michael, Scheer, Manfred
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: The Royal Society of Chemistry 2020
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159306/
https://ncbi.nlm.nih.gov/pubmed/34094126
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01740j
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