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Transformations of the cyclo-P(4) ligand in [Cp′′′Co(η(4)-P(4))]
The reactivity of the cyclo-P(4) ligand complex [Cp′′′Co(η(4)-P(4))] (1) (Cp′′′ = 1,2,4-tri-tert-butyl-cyclopentadienyl) towards reduction and main group nucleophiles was investigated. By using K[CpFe(CO)(2)], a selective reduction to the dianionic complex [(Cp′′′Co)(2)(μ,η(3):η(3)-P(8))](2−) (2) wa...
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| Veröffentlicht in: | Chem Sci |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
The Royal Society of Chemistry
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159306/ https://ncbi.nlm.nih.gov/pubmed/34094126 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01740j |
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