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Ti-catalyzed ring-opening oxidative amination of methylenecyclopropanes with diazenes
The ring-opening oxidative amination of methylenecyclopropanes (MCPs) with diazenes catalyzed by py(3)TiCl(2)(NR) complexes is reported. This reaction selectively generates branched α-methylene imines as opposed to linear α,β-unsaturated imines, which are difficult to access via other methods. Produ...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159277/ https://ncbi.nlm.nih.gov/pubmed/34123005 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01998d |
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