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Copper-catalysed photoinduced decarboxylative alkynylation: a combined experimental and computational study

Redox-active esters (RAEs) as alkyl radical precursors have demonstrated great advantages for C–C bond formation. A decarboxylative cross-coupling method is described to afford substituted alkynes from various carboxylic acids using copper catalysts CuCl and Cu(acac)(2). The photoexcitation of coppe...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Mao, Yu, Zhao, Wenxuan, Lu, Shuo, Yu, Lei, Wang, Yi, Liang, Yong, Ni, Shengyang, Pan, Yi
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159226/
https://ncbi.nlm.nih.gov/pubmed/34122950
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02213f
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