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Rationalizing the diverse reactivity of [1.1.1]propellane through σ–π-delocalization
[1.1.1]Propellane is the ubiquitous precursor to bicyclo[1.1.1]pentanes (BCPs), motifs of high value in pharmaceutical and materials research. The classical Lewis representation of this molecule places an inter-bridgehead C–C bond along its central axis; ‘strain relief’-driven cleavage of this bond...
Kaydedildi:
| Yayımlandı: | Chem Sci |
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| Asıl Yazarlar: | , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
The Royal Society of Chemistry
2020
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159217/ https://ncbi.nlm.nih.gov/pubmed/34122945 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01386b |
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