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The synthesis of brominated-boron-doped PAHs by alkyne 1,1-bromoboration: mechanistic and functionalisation studies

The synthesis of a range of brominated-B(n)-containing (n = 1, 2) polycyclic aromatic hydrocarbons (PAHs) is achieved simply by reacting BBr(3) with appropriately substituted alkynes via a bromoboration/electrophilic C–H borylation sequence. The brominated-B(n)-PAHs were isolated as either the borin...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yuan, K., Kahan, R. J., Si, C., Williams, A., Kirschner, S., Uzelac, M., Zysman-Colman, E., Ingleson, M. J.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8157679/
https://ncbi.nlm.nih.gov/pubmed/34122833
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05404a
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