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Figure-eight thermal hysteresis of aminomethylenehelicene oligomers with terminal C(16) alkyl groups during hetero-double-helix formation

1 : 1 mixtures of aminomethylenehelicene (P)-tetramer and (M)-pentamer with terminal C(16) alkyl groups in fluorobenzene showed structural changes between hetero-double-helices B and C and random-coils 2A. Figure-eight thermal hysteresis appeared when the solution was cooled and heated at a constant...

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Pubblicato in:Chem Sci
Autori principali: Sawato, Tsukasa, Iwamoto, Rina, Yamaguchi, Masahiko
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8157274/
https://ncbi.nlm.nih.gov/pubmed/34122836
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06496f
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