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“Inverse” thermoresponse: heat-induced double-helix formation of an ethynylhelicene oligomer with tri(ethylene glycol) termini
An ethynylhelicene oligomer [(M)-d-4]-C(12)-TEG with six tri(ethylene glycol) (TEG) groups at the termini was synthesized, and double-helix formation was studied using CD, UV-Vis, vapor pressure osmometry, dynamic light scattering, and (1)H NMR. [(M)-d-4]-C(12)-TEG reversibly changed its structure b...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6007355/ https://ncbi.nlm.nih.gov/pubmed/29997850 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04959h |
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