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Arylboronic Acid Catalyzed C-Alkylation and Allylation Reactions Using Benzylic Alcohols

[Image: see text] The arylboronic acid catalyzed dehydrative C-alkylation of 1,3-diketones and 1,3-ketoesters using secondary benzylic alcohols as the electrophile is reported, forming new C–C bonds (19 examples, up to 98% yield) with the release of water as the only byproduct. The process is also a...

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Publicat a:Org Lett
Autors principals: Estopiñá-Durán, Susana, Mclean, Euan B., Donnelly, Liam J., Hockin, Bryony M., Taylor, James E.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8155392/
https://ncbi.nlm.nih.gov/pubmed/32959662
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c02736
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