Exceptional Packing Density of Ammonia in a Dual-Functionalized Metal–Organic Framework

[Image: see text] We report the reversible adsorption of ammonia (NH(3)) up to 9.9 mmol g(–1) in a robust Al-based metal–organic framework, MFM-303(Al), which is functionalized with free carboxylic acid and hydroxyl groups. The unique pore environment decorated with these acidic sites results in an...

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Gepubliceerd in:J Am Chem Soc
Hoofdauteurs: Marsh, Christopher, Han, Xue, Li, Jiangnan, Lu, Zhenzhong, Argent, Stephen P., da Silva, Ivan, Cheng, Yongqiang, Daemen, Luke L., Ramirez-Cuesta, Anibal J., Thompson, Stephen P., Blake, Alexander J., Yang, Sihai, Schröder, Martin
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: American Chemical Society 2021
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8154541/
https://ncbi.nlm.nih.gov/pubmed/33885294
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c01749
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