Optimal Binding of Acetylene to a Nitro-Decorated Metal–Organic Framework

[Image: see text] We report the first example of crystallographic observation of acetylene binding to −NO(2) groups in a metal–organic framework (MOF). Functionalization of MFM-102 with −NO(2) groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO(2). However, this is cou...

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Publicat a:J Am Chem Soc
Autors principals: Duong, Thien D., Sapchenko, Sergey A., da Silva, Ivan, Godfrey, Harry G. W., Cheng, Yongqiang, Daemen, Luke L., Manuel, Pascal, Ramirez-Cuesta, Anibal J., Yang, Sihai, Schröder, Martin
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2018
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6301758/
https://ncbi.nlm.nih.gov/pubmed/30285424
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08504
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