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Understanding how Lewis acids dope organic semiconductors: a “complex” story

We report on computational studies of the potential of three borane Lewis acids (LAs) (B(C(6)F(5))(3) (BCF), BF(3), and BBr(3)) to form stable adducts and/or to generate positive polarons with three different semiconducting π-conjugated polymers (PFPT, PCPDTPT and PCPDTBT). Density functional theory...

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Publicat a:Chem Sci
Autors principals: Marqués, Pablo Simón, Londi, Giacomo, Yurash, Brett, Nguyen, Thuc-Quyen, Barlow, Stephen, Marder, Seth R., Beljonne, David
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2021
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8153436/
https://ncbi.nlm.nih.gov/pubmed/34123329
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01268a
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