Completing the triad: synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals

Oxidation of M(CO)(6) (M = Cr, Mo, W) with the synergistic oxidative system Ag[WCA]/0.5 I(2) yields the fully characterized metalloradical salts [M(CO)(6)](+)˙[WCA](−) (weakly coordinating anion WCA = [F-{Al(OR(F))(3)}(2)](−), R(F) = C(CF(3))(3)). The new metalloradical cations with M = Mo and W sho...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Bohnenberger, Jan, Schmitt, Manuel, Feuerstein, Wolfram, Krummenacher, Ivo, Butschke, Burkhard, Czajka, Jakub, Malinowski, Przemysław J., Breher, Frank, Krossing, Ingo
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8152671/
https://ncbi.nlm.nih.gov/pubmed/34094047
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc06445a
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