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A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes

We herein report a denitrogenative palladium-catalyzed cascade for the modular and regioselective synthesis of polysubstituted fluorenes. Hydrazone facilitates the Pd(ii) to Pd(iv) oxidative addition in a Catellani pathway and is also the methylene synthon in the proposed reaction. Aryl iodides and...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Fu, Wai Chung, Kwong, Fuk Yee
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8148384/
https://ncbi.nlm.nih.gov/pubmed/34123265
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04062e
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