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Synthesis of Fluorenes via the Palladium-Catalyzed 5-Exo-dig Annulation of o-Alkynyl Biaryls

The direct Pd-catalyzed intramolecular rapidly with electron-deficient benzene ring, which, in hydroarylation of o-alkynyl biaryls proceeded in highly combination with a substantial isotope effect observed, stereoselective manner producing fluorenes 2, the products of 5-exo-dig cyclization, in excel...

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Autori principali: Chernyak, Natalia, Gevorgyan, Vladimir
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2009
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2760854/
https://ncbi.nlm.nih.gov/pubmed/20160971
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.200800765
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