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Rotaxane Pt(II)-complexes: mechanical bonding for chemically robust luminophores and stimuli responsive behaviour

We report an approach to rotaxanes in which the metal ion of a cyclometallated Pt(II) luminophore is embedded in the space created by the mechanical bond. Our results show that the interlocked ligand environment stabilises a normally labile Pt(II)–triazole bond against displacement by competing liga...

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Pubblicato in:Chem Sci
Autori principali: Zhang, Zhihui, Tizzard, Graham J., Williams, J. A. Gareth, Goldup, Stephen M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8148368/
https://ncbi.nlm.nih.gov/pubmed/34123277
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05507j
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