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A Stimuli-Responsive Rotaxane–Gold Catalyst: Regulation of Activity and Diastereoselectivity

A rotaxane-based Au catalyst was developed and the effect of the mechanical bond on its behavior was studied. Unlike the non-interlocked thread, the rotaxane requires a catalytically innocent cofactor, the identity of which significantly influences both the yield and diastereoselectivity of the reac...

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發表在:Angew Chem Int Ed Engl
Main Authors: Galli, Marzia, Lewis, James E M, Goldup, Stephen M
格式: Artigo
語言:Inglês
出版: WILEY-VCH Verlag 2015
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4678423/
https://ncbi.nlm.nih.gov/pubmed/26387887
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505464
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