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A Stimuli-Responsive Rotaxane–Gold Catalyst: Regulation of Activity and Diastereoselectivity
A rotaxane-based Au catalyst was developed and the effect of the mechanical bond on its behavior was studied. Unlike the non-interlocked thread, the rotaxane requires a catalytically innocent cofactor, the identity of which significantly influences both the yield and diastereoselectivity of the reac...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autoři: | , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
WILEY-VCH Verlag
2015
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4678423/ https://ncbi.nlm.nih.gov/pubmed/26387887 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505464 |
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