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Hydrogen and proton exchange at carbon. Imbalanced transition state and mechanism crossover

A recent remarkable study of the C–H oxidation of substituted fluorenyl-benzoates together with the transfer of a proton to an internal receiving group by means of electron transfer outer-sphere oxidants, in the noteworthy absence of hydrogen-bonding interactions, is taken as an example to uncover t...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Costentin, Cyrille, Savéant, Jean-Michel
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8146334/
https://ncbi.nlm.nih.gov/pubmed/34084355
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05147c
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