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Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)(3)](−)
We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe(4)][F(ClF)(3)] as well as the homologous polychloride [NPr(3)Me][Cl(7)]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl(2), respectively. Quantum-che...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8117328/ https://ncbi.nlm.nih.gov/pubmed/33870378 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1cc01088c |
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