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Unusual Complexes of P(CH)(3) with FH, ClH, and ClF

Ab initio MP2/aug’-cc-pVTZ calculations have been performed to determine the structures and binding energies of complexes formed by phosphatetrahedrane, P(CH)(3), and HF, HCl, and ClF. Four types of complexes exist on the potential energy surfaces. Isomers A form at the P atom near the end of a P-C...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Del Bene, Janet E., Alkorta, Ibon, Elguero, José
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7356268/
https://ncbi.nlm.nih.gov/pubmed/32575624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25122846
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