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Unusual Complexes of P(CH)(3) with FH, ClH, and ClF

Ab initio MP2/aug’-cc-pVTZ calculations have been performed to determine the structures and binding energies of complexes formed by phosphatetrahedrane, P(CH)(3), and HF, HCl, and ClF. Four types of complexes exist on the potential energy surfaces. Isomers A form at the P atom near the end of a P-C...

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Publicado en:Molecules
Autores principales: Del Bene, Janet E., Alkorta, Ibon, Elguero, José
Formato: Artigo
Lenguaje:Inglês
Publicado: MDPI 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7356268/
https://ncbi.nlm.nih.gov/pubmed/32575624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules25122846
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