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Palladium-Mediated C(γ)—H Functionalization of Alicyclic Amines
This paper describes a new method for the transannular functionalization of the γ-C-H bonds in alicyclic amines to install C(sp(3))–halogen, oxygen, nitrogen, boron, and sulfur bonds. The key challenge for this transformation is controlling the relative rate of C(γ)–H versus C(α)–H functionalization...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8102420/ https://ncbi.nlm.nih.gov/pubmed/33720500 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202101782 |
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