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Model Complexes for the Palladium-Catalyzed Transannular C–H Functionalization of Alicyclic Amines

This report describes the synthesis of model complexes for key intermediates in the Pd-catalyzed transannular C(sp(3))–H arylation of alicyclic amines. These complexes react stoichiometrically with phenyl iodide to afford C–H arylation products. Furthermore, they participate in H/D exchange with d(1...

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Detalhes bibliográficos
Publicado no:Organometallics
Main Authors: Aguilera, Ellen Y., Sanford, Melanie S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6527359/
https://ncbi.nlm.nih.gov/pubmed/31118540
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00533
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