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One-Pot Synthesis of (Z)-β-Halovinyl Ketones via the Cascade of Sonogashira Coupling and Hydrohalogenation

Herein, we report an efficient method for the synthesis of (Z)-β-halovinyl ketones through a one-pot Sonogashira coupling and hydrohalogenation reaction promoted by palladium-copper catalyst and Brønsted acid. The ynone intermediates are generated in situ from readily available acid chlorides and te...

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Detalhes bibliográficos
Publicado no:Front Chem
Main Authors: Chen, Fa-Jie, Hua, Zhenguo, Chen, Jianhui, Chen, Jiajia, Lee, Daesung, Xia, Yuanzhi
Formato: Artigo
Idioma:Inglês
Publicado em: Frontiers Media S.A. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8100659/
https://ncbi.nlm.nih.gov/pubmed/33968892
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2020.621545
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