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Stereospecific Electrophilic Fluorination of Alkylcarbastannatrane Reagents

We report the use of isolable primary and secondary alkylcarbastannatrane nucleophiles in site-specific fluorination reactions. These reactions occur without the need for transition metal catalysis or in situ activation of the nucleophile. In the absence of the carbastannatrane backbone, alkyltin nu...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Ma, Xinghua, Diane, Mohamed, Ralph, Glenn, Chen, Christine, Biscoe, Mark R.
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8054978/
https://ncbi.nlm.nih.gov/pubmed/28833888
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704672
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