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α‐Diazo Sulfonium Triflates: Synthesis, Structure, and Application to the Synthesis of 1‐(Dialkylamino)‐1,2,3‐triazoles

The one‐pot synthesis of a series of sulfonium salts containing transferable diazomethyl groups is described, and the structure of these compounds is elucidated by X‐ray crystallography. Under photochemical conditions, reaction of these salts with N,N‐dialkyl hydrazones affords 1‐(dialkylamino)‐1,2,...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Li, Xiangdong, Golz, Christopher, Alcarazo, Manuel
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8048477/
https://ncbi.nlm.nih.gov/pubmed/33351262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014775
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