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α‐Diazo Sulfonium Triflates: Synthesis, Structure, and Application to the Synthesis of 1‐(Dialkylamino)‐1,2,3‐triazoles

The one‐pot synthesis of a series of sulfonium salts containing transferable diazomethyl groups is described, and the structure of these compounds is elucidated by X‐ray crystallography. Under photochemical conditions, reaction of these salts with N,N‐dialkyl hydrazones affords 1‐(dialkylamino)‐1,2,...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Li, Xiangdong, Golz, Christopher, Alcarazo, Manuel
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2021
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8048477/
https://ncbi.nlm.nih.gov/pubmed/33351262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014775
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