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A Mild One-Pot Reduction of Phosphine(V) Oxides Affording Phosphines(III) and Their Metal Catalysts

[Image: see text] The metal-free reduction of a range of phosphine(V) oxides employing oxalyl chloride as an activating agent and hexachlorodisilane as reducing reagent has been achieved under mild reaction conditions. The method was successfully applied to the reduction of industrial waste byproduc...

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Bibliografiske detaljer
Udgivet i:Organometallics
Main Authors: Kapuśniak, Łukasz, Plessow, Philipp N., Trzybiński, Damian, Woźniak, Krzysztof, Hofmann, Peter, Jolly, Phillip Iain
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2021
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8043083/
https://ncbi.nlm.nih.gov/pubmed/33867621
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.0c00788
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