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A Dual Site Catalyst for Mild, Selective Nitrile Reduction
We report a novel ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction. The pre-catalyst compound {[κ(3)-(1-pz)(2)HB(N=CHCH(3))]Ru(cymene)}(+) TfO(−) (pz = pyrazolyl) was synth...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3999263/ https://ncbi.nlm.nih.gov/pubmed/24409456 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc47384h |
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