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A Dual Site Catalyst for Mild, Selective Nitrile Reduction

We report a novel ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction. The pre-catalyst compound {[κ(3)-(1-pz)(2)HB(N=CHCH(3))]Ru(cymene)}(+) TfO(−) (pz = pyrazolyl) was synth...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Lu, Zhiyao, Williams, Travis J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2014
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3999263/
https://ncbi.nlm.nih.gov/pubmed/24409456
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc47384h
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