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How the Lewis Base F(–) Catalyzes the 1,3-Dipolar Cycloaddition between Carbon Dioxide and Nitrilimines
[Image: see text] The mechanism of the Lewis base F(–) catalyzed 1,3-dipolar cycloaddition between CO(2) and nitrilimines is interrogated using DFT calculations. F(–) activates the nitrilimine, not CO(2) as proposed in the literature, and imparts a significant rate enhancement for the cycloaddition....
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| Pubblicato in: | J Org Chem |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical
Society
2021
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8023701/ https://ncbi.nlm.nih.gov/pubmed/33577314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c02963 |
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