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Antimony–Oxo Porphyrins as Photocatalysts for Redox-Neutral C–H to C–C Bond Conversion

[Image: see text] The use of high-valent antimony–oxo porphyrins as visible-light photocatalysts operating via direct hydrogen atom transfer has been demonstrated. Computational analysis indicates that the triplet excited state of these complexes shows an oxyl radical behavior, while the Sb(V) cente...

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Publicat a:ACS Catal
Autors principals: Capaldo, Luca, Ertl, Martin, Fagnoni, Maurizio, Knör, Günther, Ravelli, Davide
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8009479/
https://ncbi.nlm.nih.gov/pubmed/33815891
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c02250
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