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Mild, Redox-Neutral Alkylation of Imines Enabled by an Organic Photocatalyst

[Image: see text] An operationally simple, mild, redox-neutral method for the photoredox alkylation of imines is reported. Utilizing an inexpensive organic photoredox catalyst, alkyl radicals are readily generated from the single-electron oxidation of ammonium alkyl bis(catecholato)silicates and are...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Patel, Niki R., Kelly, Christopher B., Siegenfeld, Allison P., Molander, Gary A.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5369175/
https://ncbi.nlm.nih.gov/pubmed/28367354
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b03665
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