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N,N‐Dialkylhydrazones as Versatile Umpolung Reagents in Enantioselective Anion‐Binding Catalysis
An enantioselective anion‐binding organocatalytic approach with versatile N,N‐dialkylhydrazones (DAHs) as polarity‐reversed (umpolung) nucleophiles is presented. For the application of this concept, a highly ordered hydrogen‐bond (HB) network between a carefully selected CF(3)‐substituted triazole‐b...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
|---|---|
| Hoofdauteurs: | , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2021
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986925/ https://ncbi.nlm.nih.gov/pubmed/33306858 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013380 |
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