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Efficient Amination of Activated and Non‐Activated C(sp(3))−H Bonds with a Simple Iron–Phenanthroline Catalyst
A readily available catalyst consisting of iron dichloride in combination with 1,10‐phenanthroline catalyzes the ring‐closing C−H amination of N‐benzoyloxyurea to form imidazolidin‐2‐ones in high yields. The C−H amination reaction is very general and applicable to benzylic, allylic, propargylic, and...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2021
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986731/ https://ncbi.nlm.nih.gov/pubmed/33301240 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013687 |
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