Intramolecular C(sp(3))–H Bond Oxygenation by Transition‐Metal Acylnitrenoids

This study demonstrates for the first time that easily accessible transition‐metal acylnitrenoids can be used for controlled direct C(sp(3))‐H oxygenations. Specifically, a ruthenium catalyst activates N‐benzoyloxycarbamates as nitrene precursors towards regioselective intramolecular C−H oxygenation...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Tan, Yuqi, Chen, Shuming, Zhou, Zijun, Hong, Yubiao, Ivlev, Sergei, Houk, K. N., Meggers, Eric
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Research Articles
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756817/
https://ncbi.nlm.nih.gov/pubmed/32729945
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009335
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