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Carbo[n]helicenes Restricted to Enantiomerize: An Insight into the Design Process of Configurationally Stable Functional Chiral PAHs

The most important stereodynamic feature of carbo[n]helicenes is the interconversion of their enantiomers. The Gibbs activation energy (ΔG (≠)(T)) of this process, which determines the rate of enantiomerization, dictates the configurational stability of [n]helicenes. High values of ΔG (≠)(T) are req...

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Publicat a:Chemistry
Autor principal: Ravat, Prince
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986117/
https://ncbi.nlm.nih.gov/pubmed/33034405
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004488
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